Three-season rotation of chicory-tobacco-peanut with high biomass and bioconcentration factors effectively remediates cadmium-contaminated farmland.

Traditional phytoremediation is one approach to remediate heavy metal pollution. In developing countries, the key factor in promoting practical application of phytoremediation in polluted soils is selecting suitable plants that are tolerant to heavy metals and also produce products with economic value. Therefore, a field experiment was conducted with a three-season chicory-tobacco-peanut rotation to determine effects on remediation of cadmium (Cd)-contaminated farmland in China. All crops had strong Cd accumulation capacity, with bioconcentration factors of 6.61 to 11.97 in chicory, 3.85 to 21.61 in tobacco, and 1.36 to 7.0 in peanut. Yield of total dry biomass reached 32.4 t ha-1, and the Cd phytoextraction efficiency was 10.3% per year. Aboveground tissues of the three crops accounted for 83.9 to 91.2% of total biomass in the rotation experiment. Cd content in peanut grain and oil met the National Food Safety Standard of China (0.5 mg kg-1, GB 2762-2017) and the Food Contaminant Limit of the European Union (0.1 mg kg-1, 18,812,006). Therefore, in addition to phytoremediation of Cd-contaminated soils, the chicory-tobacco-peanut rotation system can also produce economic benefits for local farmers.

Quantum optimal control of multiple weakly interacting molecular rotors in the time-dependent Hartree approximation.

We perform quantum optimal control simulations, based on the Time-Dependent Hartree (TDH) approximation, for systems of three to five dipole-dipole coupled OCS rotors. A control electric field is used to steer all of the individual rotors, arranged in chains and regular polygons in a plane, toward either identical or unique objectives. The goal is to explore the utility of the TDH approximation to model the field-induced dynamics of multiple interacting rotors in the weak dipole-dipole coupling regime. A stochastic hill climbing approach is employed to seek an optimal control field that achieves the desired objectives at a specified target time. We first show that multiple rotors in chain and polygon geometries can be identically oriented in the same direction; these cases do not significantly depend on the presence of the dipole-dipole interaction. Additionally, in particular geometrical arrangements, we demonstrate that individual rotors can be uniquely manipulated toward different objectives with the same field. Specifically, it is shown that for a three rotor chain, the two end rotors can be identically oriented in a specific direction while keeping the middle rotor in its ground state, and for an equilateral triangle, two rotors can be identically oriented in a specific direction while the third rotor is oriented in the opposite direction. These multirotor unique objective cases exploit the shape of the field in coordination with dipole-dipole coupling between the rotors. Comparisons to numerically exact calculations, utilizing the TDH-determined fields, are given for all optimal control studies involving systems of three rotors.

Cadmium accumulation in winter crops and the assessment of paddy soil phytoremediation in southern China.

Heavy metal pollution, in particular with cadmium (Cd), threatens both the environment and human health. The phytoremediation of contaminated soil is one recently developed eco-friendly technique that can be applied to mitigate this issue. Repairing Cd-contaminated paddy soil during the fallow winter period can ensure future rice production while reducing heavy metal pollution. Seven winter crops were planted in this study to investigate the accumulation of this metal in mid-level Cd and low-level lead (Pb) and zinc (Zn)-contaminated paddy soils. Results show that after 4 or 5 months of growth, all crops had become moderately tolerant to toxicity; indeed, shoot Cd bioconcentration factor (BCF) values were 37.4, 17.0, 11.5, 10.5, 5.8, 3.9, and 1.4 for Sedum alfredii (SA), Witloof chicory (WC), edible-leaf beet (EB), Cardamine hupingshanensis (CH), leafy mustard (LM), oil mustard (OM), and perennial ryegrass (PR), respectively, while shoot Pb and Zn BCF values were less than 1 and 5, respectively. And SA, WC, EB, and CH all had higher shoot Cd accumulation capacities, especially SA in which the level reached 53.9 mg kg-1. The calculation results of restoration potential show that it will take at least 5 years for WC, 7 years for SA and EB, and 10 years for CH to reach the repair target. These results show that it is possible to grow winter crops to repair soil Cd pollution, with WC, EB, CH, and SA, the best candidates for making full use of fallow periods while simultaneously achieving soil phytoremediation. The results of this study will prove useful for establishing a new summer production model by ensuring the winter repair of contaminated paddy soil.